Bis(3-benzoyl-1,1-di-sec-butylthioureato-κ2 O,S)palladium(II)
نویسندگان
چکیده
The complex mol-ecule of the title complex, [Pd(C(16)H(23)N(2)OS)(2)], is completed by crystallographic twofold symmetry with the metal atom lying on the rotation axis. The Pd(II) atom exists within a slightly distorted square-planar geometry defined by a cis-O(2)S(2) donor set. The dihedral angle formed between the mean planes of the symmetry-related six-membered chelate rings is 12.88 (7)° and the bond lengths within the rings are indicative of significant electron delocalization. In the crystal, mol-ecules aggregate into dimers linked by four C-H⋯O inter-actions.
منابع مشابه
(Acetato-κ2 O,O′)[2′-(di-tert-butylphosphanyl)-1,1′-biphenyl-κ2 P,C 2]palladium(II)
The structure of the title compound, [Pd(C(2)H(3)O(2))(C(20)H(26)P)], shows a distorted square-planar geometry for the Pd(II) atom, with significant deviations being evident owing to the asymmetric coordination mode of the acetate ligand. A weak intra-molecular C-H⋯O inter-action is noted. The crystal studied was a racemic twin.
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